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Type: Artigo de periódico
Title: Application of toxicity identification evaluation to sediment in a highly contaminated water reservoir in southeastern Brazil
Author: Araujo, RPA
Botta-Paschoal, CMR
Silverio, PF
Almeida, FV
Rodrigues, PE
Umbuzeiro, GA
Jardim, WF
Mozeto, AA
Abstract: Rasgao Reservoir, located close to the Metropolitan region of Sao Paulo, Brazil, has been analyzed previously, and its sediment was found to be highly toxic, with high levels of metals and polycyclic aromatic hydrocarbons and a complete absence of benthic life. Polychlorinated biphenyls also were present, as was mutagenic activity, detected with the Salmonella/microsome assay. Because of the extremely complex mixture of contaminants in these sediments, a toxicity identification evaluation was performed on the pore water and elutriate using Ceriodaphnia dubia and Vibrio fischeri. Toxicity characterization, identification, and confirmation procedures were performed in one representative sample of the reservoir, and the results indicated that ammonia was the main cause of the toxicity detected with C. dubia in both sediment pore water and elutriate. Chemical analysis corroborated this observation by revealing un-ionized ammonia concentrations as high as 5.14 mg/L in pore water and 2.06 mg/L in elutriate. These high ammonia levels masked possible toxicity caused by other classes of compounds. The toxicity detected with V. fischeri decreased with the time of sample storage and was related to the organic fraction of the pore water and the elutriate, in which compounds such as benzothiazole and nonylphenol were detected.
Subject: sediment
toxicity identification evaluation
Ceriodaphnia dubia
Vibrio fischeri
Country: EUA
Editor: Setac
Rights: fechado
Identifier DOI: 10.1897/05-144R.1
Date Issue: 2006
Appears in Collections:Unicamp - Artigos e Outros Documentos

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