Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/54759
Type: Artigo de periódico
Title: Application of natural and modified hectorite clays as adsorbents to removal of Cr(VI) from aqueous solution-Thermodynamic and equilibrium study (Retracted article. See vol. 194, pg. 446, 2011)
Author: Guerra, DL
Viana, RR
Airoldi, C
Abstract: A hectorite (H) clay sample has been modified with 2-mercaptobenzimidazole (MBI) using homogeneous and heterogeneous routes. Both modification methodologies resulted in similar products. named H(HOM) and H(HET), respectively. These materials were characterized by CO(2) gas adsorption, elemental analysis. nuclear magnetic nuclei of carbon-13 and silicon-29. The effect of two variables (contact time and metal concentration) has been studied using batch technique at room temperature and pH 2.0. After achieving the best conditions for Cr(VI) adsorption, isotherms of this adsorbate on using the chosen adsorbents were obtained, which were fitted to non-linear Sips isotherm model. The maximum number of moles adsorbed was determined to be 11.63, 12.85 and 14.01 mmol g(-1) for H, H(HOM) and H(HET), respectively. reflecting the maximum adsorption order of H(HET) > H(HOM) > H. The energetic effects (Delta(int)H degrees, Delta(int)G degrees, and Delta(int)S degrees) caused by chromium ion adsorption were determined through calorimetric titrations. (C) 2009 Published by Elsevier B.V
Subject: Hectorite
Chromium
Adsorption
Thermodynamic
Country: Holanda
Editor: Elsevier Science Bv
Rights: fechado
Identifier DOI: 10.1016/j.jhazmat.2009.07.016
Date Issue: 2009
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

Files in This Item:
File Description SizeFormat 
WOS000271346800069.pdf57.51 kBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.