Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/54591
Type: Artigo de periódico
Title: Analysis of powdered coffee and milk by ICPOES after sample treatment with tetramethylammonium hydroxide
Author: Ribeiro, AS
Moretto, AL
Arruda, MAZ
Cadore, S
Abstract: A simple method for the solubilization of powdered milk and soluble coffee using tetramethylammonium hydroxide (TMAH) is proposed. While 500 muL of the reagent was used for the solubilization of 350 mg of coffee samples, milk samples required 1000 muL of TMAH. Solubilization at 80degreesC takes place within 10, 20 and 30 min for soluble coffee, whole and skim powdered milk, respectively. Subsequently, the volume was topped up to 25 mL with deionized water. Thereafter, the concentrations of Ca, Cu, Fe, K, Mg, Mn, Na, P, Se, Sn and Zn were determined by inductively coupled plasma optical emission spectrometry (ICP OES). When applied to standard reference material and to commercial samples the proposed method showed good results, and it was also compared with two other preparation methods. Limits of detection calculated for Ca, Cu, Fe, K, Mg, Mn, Na, P, Se, Sri and Zn were 2.1, 0.065, 0.11, 103, 0.08 8, 0.011, 1.5, 2. 1, 1.1, 0.66 and 0.11 mug g(-1) respectively. The RSD values were less than 10% for the certified reference materials (IAEAA-11 and BCR 63R). Statistical tests showed that the results for the metal concentrations do not vary significantly with the different methods or with the certified reference values, considering a confidence limit of 95%.
Subject: inductively coupled plasma optical emission spectrometry
tetramethylammonium hydroxide
soluble coffee
powdered milk
slurry
Country: Austria
Editor: Springer-verlag Wien
Rights: fechado
Identifier DOI: 10.1007/s00604-002-0935-3
Date Issue: 2003
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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