Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/54118
Type: Artigo de periódico
Title: Acidity control of ruthenium pillared clay and its application as a catalyst in hydrogenation reactions
Author: Figueiredo, FCA
Jordao, E
Landers, R
Carvalho, WA
Abstract: Aluminum pillared clay was used as a support for the preparation of catalysts containing ruthenium as active metal, in the presence or not of a promoter (tin) and an acid reducer (barium). The catalysts were characterized and tested for hydrogenation of dimethyl adipate reactions. The results showed a high conversion, typically above 95%. in all studied systems. This conversion occurs irrespectively of the presence of active metal; therefore, it may be due to the support's intrinsic activity. The acidity was identified as the main cause of this activity. A barium treatment of these catalysts significantly reduced this acidity, thus making more selective the available systems. The catalysts treated with barium reduced the formation of undesirable products up to 45%. Similarly, the presence of tin helped to obtain valuable products such as gamma-caprolactone and methyl caproate, which reached high selectivity values (18.6% and 16.9%, respectively). (C) 2009 Elsevier B.V. All rights reserved.
Subject: Pillared clay
Hydrogenation
Ruthenium
Acidity control
Adipate
Lactones
Country: Holanda
Editor: Elsevier Science Bv
Rights: fechado
Identifier DOI: 10.1016/j.apcata.2009.09.039
Date Issue: 2009
Appears in Collections:Unicamp - Artigos e Outros Documentos

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