Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/53962
Type: Artigo de periódico
Title: A very low potential electrochemical detection of L-cysteine based on a glassy carbon electrode modified with multi-walled carbon nanotubes/gold nanorods
Author: Silva, FDD
da Silva, MGA
Lima, PR
Meneghetti, MR
Kubota, LT
Goulart, MOF
Abstract: A nanohybrid platform built with multi-walled carbon nanotubes and gold nanorods, prepared via a cationic surfactant-containing seed-mediated sequential growth process, in aqueous solution, on a glassy carbon substrate has been successfully developed to be used in the electrocatalytic oxidation of L-cysteine (Cys). The nanohybrid was characterized by transmission electron microscopy, Raman spectroscopy and electrochemical measurements. Cyclic voltammetry results had shown that the modified electrode allows the oxidation of Cys at a very low anodic potential (0.00 V vs. Ag/AgCl). The kinetic constant k(cat) for the catalytic oxidation of Cys was evaluated by chronoamperometry and provided a value of 5.6 x 10(4) L mol(-1) s(-1). The sensor presents a linear response range from 5.0 up to 200.0 mu mol L-1, detection limit of 8.25 nmol L-1 and a sensitivity of 120 nA L mu mol(-1). (C) 2013 Elsevier B.V. All rights reserved.
Subject: Gold nanorods
MWCNT
L-cysteine
Electrocatalysis
Chemically modified electrodes
Country: Inglaterra
Editor: Elsevier Advanced Technology
Rights: fechado
Identifier DOI: 10.1016/j.bios.2013.06.036
Date Issue: 2013
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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