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Type: Artigo de periódico
Title: (Z)-Ethyl 2-hydroxyimino-2-(4-nitrobenzyl)ethanoate
Author: Caracelli, I
Trindade, AC
Moran, PJS
Hinoue, L
Zukerman-Schpector, J
Tiekink, ERT
Abstract: The title molecule, C(11)H(10)N(2)O(6), has a Z conformation about the C = N bond of the oxime unit. There are significant twists from planarity throughout the molecule, the most significant being between the hydroxyimino and ester groups which are effectively orthogonal with an N-C-C-O(carbonyl) torsion angle of 91.4 (2)degrees. The crystal packing features oxime-benzoyl O-H center dot center dot center dot O contacts that lead to chains along [010] and C-H center dot center dot center dot O interactions also occur.
Country: EUA
Editor: Wiley-blackwell
Rights: aberto
Identifier DOI: 10.1107/S1600536809052386
Date Issue: 2010
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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