Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/52398
Type: Artigo de periódico
Title: Novel C-H activation in a bis-tetrairidium carbonyl complex of the sandwich compound [Fe(eta(5)-C5H5)(eta(5)-P(3)C(2)Bu(2)(t))]: Crystal and molecular structures of [Ir-4(CO)(11){Fe(eta(5)-C5H5)(eta(5)-P(3)C(2)Bu(2)(t))}] and [HIr4(CO)(10)-{mu-Fe(eta(5)-C5H5)(eta(5)-P3CH2(CMe(2))CBu(t))}Ir-4(CO)(11)]
Author: Benvenutti, MHA
Hitchcock, PB
Nixon, JF
Vargas, MD
Abstract: The syntheses and structural determinations of novel complexes of the type [Ir-4(CO)(11)L] {L = [Fe(eta(5)-P(3)C(2)Bu(2)(t))(eta(5)-P(2)C(3)Bu(3)(t))] or [Fe(eta(5)-C5H5)(eta(5)-P(3)C(2)Bu(2)(t))]} and [HIr4(CO)(10){mu-Fe(eta(5)-C5H5)(eta(5)-P3CH2(CMe(2))CBu(t))}Ir-4(CO)(11)], involving an unusual C-H activation, are described.
Country: Inglaterra
Editor: Royal Soc Chemistry
Rights: embargo
Identifier DOI: 10.1039/cc9960000441
Date Issue: 1996
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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