Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/356097
Type: Artigo
Title: Structure and biogenesis of Roussoellatide, a dichlorinated polyketide from the marine-derived fungus Roussoella sp DLM33
Author: Ferreira, Everton L. F.
Williams, David E.
Ioca, Laura P.
Morais-Urano, Raquel P.
Santos, Mario F. C.
Patrick, Brian O.
Elias, Luciana M.
Lira, Simone P.
Ferreira, Antonio G.
Passarini, Michel R. Z.
Sette, Lara D.
Andersen, Raymond J.
Berlinck, Roberto G. S.
Abstract: The structure of the fungal metabolite roussoellatide (1) has been established by spectroscopic and X-ray diffraction analyses. Results from feeding experiments with [1-C-13]acetate, [2-C-13]acetate, and [1,2-C-13]acetate were consistent with a biosynthetic pathway to the unprecedented skeleton of 1 involving Favorskii rearrangements in separate pentaketides, subsequently joined via an intermolecular Diels-Alder reaction
Subject: Metabólitos
Policetídeos
Country: Estados Unidos
Editor: American Chemical Society
Rights: Fechado
Identifier DOI: 10.1021/acs.orglett.5b02060
Address: https://pubs.acs.org/doi/10.1021/acs.orglett.5b02060
Date Issue: 2015
Appears in Collections:CPQBA - Artigos e Outros Documentos

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