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dc.contributor.CRUESPUNIVERSIDADE ESTADUAL DE CAMPINASpt_BR
dc.contributor.authorunicampSantos, Gustavo Macedo de Paula-
dc.typeArtigopt_BR
dc.titleA large epeiric methanogenic Bambuí sea in the core of Gondwana supercontinent?pt_BR
dc.contributor.authorCaetano-Filho, Sergio-
dc.contributor.authorSansjofre, Pierre-
dc.contributor.authorAder, Magali-
dc.contributor.authorPaula-Santos, Gustavo M.-
dc.contributor.authorGuacaneme, Cristian-
dc.contributor.authorBabinski, Marly-
dc.contributor.authorBedoya-Rueda, Carolina-
dc.contributor.authorKuchenbecker, Matheus-
dc.contributor.authorReis, Humberto L.S.-
dc.contributor.authorTrindade, Ricardo I.F.-
dc.subjectCarbono - Isótopospt_BR
dc.subject.otherlanguageCarbon - Isotopespt_BR
dc.description.abstractCarbon isotope compositions of both sedimentary carbonate and organic matter can be used as key proxies of the global carbon cycle and of its evolution through time, as long as they are acquired from waters where the dissolved inorganic carbon (DIC) is in isotope equilibrium with the atmospheric CO2. However, in shallow water platforms and epeiric settings, the influence of local to regional parameters on carbon cycling may lead to DIC isotope variations unrelated to the global carbon cycle. This may be especially true for the terminal Neoproterozoic, when Gondwana assembly isolated waters masses from the global ocean, and extreme positive and negative carbon isotope excursions are recorded, potentially decoupled from global signals. To improve our understanding on the type of information recorded by these excursions, we investigate the paired δ13Ccarb and δ13Corg evolution for an increasingly restricted late Ediacaran-Cambrian foreland system in the West Gondwana interior: the basal Bambuí Group. This succession represents a 1st-order sedimentary sequence and records two major δ13Ccarb excursions in its two lowermost lower-rank sequences. The basal cap carbonate interval at the base of the first sequence, deposited when the basin was connected to the ocean, hosts antithetical negative and positive excursions for δ13Ccarb and δ13Corg, respectively, resulting in Δ13C values lower than 25‰. From the top of the basal sequence upwards, an extremely positive δ13Ccarb excursion is coupled to δ13Corg, reaching values of +14‰ and −14‰, respectively. This positive excursion represents a remarkable basin-wide carbon isotope feature of the Bambuí Group that occurs with only minor changes in Δ13C values, suggesting change in the DIC isotope composition. We argue that this regional isotopic excursion is related to a disconnection between the intrabasinal and the global carbon cycles. This extreme carbon isotope excursion may have been a product of a disequilibria between the basin DIC and atmospheric CO2 induced by an active methanogenesis, favored by the basin restriction. The drawdown of sulfate reservoir by microbial sulfate reduction in a poorly ventilated and dominantly anoxic basin would have triggered methanogenesis and ultimately methane escape to the atmosphere, resulting in a13C-enriched DIC influenced by methanogenic CO2. Isolated basins in the interior of the Gondwana supercontinent may have represented a significant source of methane inputs to the atmosphere, potentially affecting both the global carbon cycle and the climatept_BR
dc.relation.ispartofGeoscience frontierspt_BR
dc.publisher.cityAmsterdampt_BR
dc.publisher.countryPaíses Baixospt_BR
dc.publisherElsevierpt_BR
dc.date.issued2021-
dc.date.monthofcirculationJan.pt_BR
dc.language.isoengpt_BR
dc.description.volume12pt_BR
dc.description.issuenumber1pt_BR
dc.description.firstpage203pt_BR
dc.description.lastpage218pt_BR
dc.rightsFechadopt_BR
dc.sourceWOSpt_BR
dc.identifier.issn1674-9871pt_BR
dc.identifier.eissn2588-9192pt_BR
dc.identifier.doi10.1016/j.gsf.2020.04.005pt_BR
dc.identifier.urlhttps://www.sciencedirect.com/science/article/pii/S1674987120300955pt_BR
dc.description.sponsorshipFUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESPpt_BR
dc.description.sponsordocumentnumber2016/06114-6; 400764/2016-4; 2016/11496-5; 2017/00399-1pt_BR
dc.date.available2021-02-17T14:18:30Z-
dc.date.accessioned2021-02-17T14:18:30Z-
dc.description.provenanceSubmitted by Susilene Barbosa da Silva (susilene@unicamp.br) on 2021-02-17T14:18:30Z No. of bitstreams: 0en
dc.description.provenanceMade available in DSpace on 2021-02-17T14:18:30Z (GMT). No. of bitstreams: 0 Previous issue date: 2021en
dc.identifier.urihttp://repositorio.unicamp.br/jspui/handle/REPOSIP/355968-
dc.contributor.departmentSem informaçãopt_BR
dc.contributor.unidadeInstituto de Geociênciaspt_BR
dc.subject.keywordEdiacaranpt_BR
dc.subject.keywordMethanogenesispt_BR
dc.identifier.source000597401000014pt_BR
dc.creator.orcid0000-0001-9630-1243pt_BR
dc.type.formArtigo de pesquisapt_BR
dc.description.sponsorNoteThis study was funded by the São Paulo Research Foundation (FAPESP) thematic project grant #2016/06114-6 and Brazilian Research Council project grant #400764/2016-4. We acknowledge to Lhoist and Petra Energia S.A. for providing drill core samples, and to Pôle de Spectométrie Océan staff, University of Western Brittany, for the technical support in data acquisition. Sergio Caetano Filho holds a FAPESP scholarship grant #2016/11496-5. Gustavo M. Paula-Santos holds a FAPESP post-doc grant #2017/00399-1. Marly Babinski, Ricardo Trindade and Matheus Kuchenbecker are fellows of the Brazilian Research Council (#307563/2013-8, #206997/2014-0 and #309106/2017-6, respectively). This study contributes to the IdEx Université de Paris ANR-18-IDEX-0001 and to the LabexMER ANR-10-LABX-19. IPGP contribution No. 4103. Finally, we thank to Prof. Linda Kah and Prof. Gabriel Uhlein for their helpful and constructive reviews which improved this manuscript, and to the Prof. Richard Damian Nance for the careful editorial handlingpt_BR
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