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Type: Outro documento
Title: Stereoselective synthesis of 3-hydroxy-4-arylcyclopentanones and 4-arylcyclopentenones through a heck-matsuda desymmetrization of meso Cis-4-cyclopentene-1,3-diol
Author: Carmona, Rafaela C.
Correia, Carlos Roque D.
Abstract: A new palladium-catalyzed route to 3-hydroxy-4-arylcyclopentanones and 4-arylcyclopentenones in a diastereo- and enantioselective manner by a Heck-Matsuda desymmetrization was achieved from the commercially available meso cis-4-cyclopentene-1,3-diol. This method is highly practical, mild, high yielding and is carried out under "open vessel" conditions. Protected and unprotected substrates provide distinct products bearing considerable value as synthetic scaffolds for the synthesis of natural and unnatural bioactive compounds containing a five-membered ring
Subject: Arilação enantiosseletiva
Heck-Matsuda, reação de
Country: Alemanha
Editor: John Wiley & Sons
Rights: Fechado
Identifier DOI: 10.1002/adsc.201500281
Date Issue: 2015
Appears in Collections:IQ - Artigos e Outros Documentos

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