The total synthesis of (-)-cryptocaryol A

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Type:	Artigo
Title:	The total synthesis of (-)-cryptocaryol A
Author:	Dias, L. C. Kuroishi, P. K. de Lucca Junior, E. C.
Abstract:	A stereoselective total synthesis of (-)-cryptocaryol A (1) is described. Key features of the 17-step route include the use of three boron-mediated aldol reaction-reduction sequences to control all stereocenters and an Ando modification of the Horner-Wadsworth-Emmons olefination that permitted the installation of the Z double bond of the alpha-pyrone ring
Subject:	Criptocariol A Reação aldólica
Country:	Estados Unidos
Editor:	Royal Society of Chemistry
Rights:	Aberto
Identifier DOI:	10.1039/c5ob00080g
Address:	https://pubs.rsc.org/en/content/articlelanding/2015/OB/C5OB00080G
Date Issue:	2015
Appears in Collections:	IQ - Artigos e Outros Documentos

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