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Type: | Artigo |
Title: | The total synthesis of (-)-cryptocaryol A |
Author: | Dias, L. C. Kuroishi, P. K. de Lucca Junior, E. C. |
Abstract: | A stereoselective total synthesis of (-)-cryptocaryol A (1) is described. Key features of the 17-step route include the use of three boron-mediated aldol reaction-reduction sequences to control all stereocenters and an Ando modification of the Horner-Wadsworth-Emmons olefination that permitted the installation of the Z double bond of the alpha-pyrone ring |
Subject: | Criptocariol A Reação aldólica |
Country: | Estados Unidos |
Editor: | Royal Society of Chemistry |
Rights: | Aberto |
Identifier DOI: | 10.1039/c5ob00080g |
Address: | https://pubs.rsc.org/en/content/articlelanding/2015/OB/C5OB00080G |
Date Issue: | 2015 |
Appears in Collections: | IQ - Artigos e Outros Documentos |
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