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|Title:||The total synthesis of (-)-cryptocaryol A|
|Author:||Dias, L. C.|
Kuroishi, P. K.
de Lucca Junior, E. C.
|Abstract:||A stereoselective total synthesis of (-)-cryptocaryol A (1) is described. Key features of the 17-step route include the use of three boron-mediated aldol reaction-reduction sequences to control all stereocenters and an Ando modification of the Horner-Wadsworth-Emmons olefination that permitted the installation of the Z double bond of the alpha-pyrone ring|
|Editor:||Royal Society of Chemistry|
|Appears in Collections:||IQ - Artigos e Outros Documentos|
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