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Type: Artigo
Title: The total synthesis of (-)-cryptocaryol A
Author: Dias, L. C.
Kuroishi, P. K.
de Lucca Junior, E. C.
Abstract: A stereoselective total synthesis of (-)-cryptocaryol A (1) is described. Key features of the 17-step route include the use of three boron-mediated aldol reaction-reduction sequences to control all stereocenters and an Ando modification of the Horner-Wadsworth-Emmons olefination that permitted the installation of the Z double bond of the alpha-pyrone ring
Subject: Criptocariol A
Reação aldólica
Country: Estados Unidos
Editor: Royal Society of Chemistry
Rights: Aberto
Identifier DOI: 10.1039/c5ob00080g
Date Issue: 2015
Appears in Collections:IQ - Artigos e Outros Documentos

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