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dc.contributor.CRUESPUNIVERSIDADE ESTADUAL DE CAMPINASpt_BR
dc.contributor.authorunicampCormanich, Rodrigo Antonio-
dc.contributor.authorunicampRittner Neto, Roberto-
dc.typeArtigopt_BR
dc.titleConformational preferences of AC-GLY-NHME in solutionpt_BR
dc.contributor.authorCormanich, R. A.-
dc.contributor.authorRittner, R.-
dc.contributor.authorBuehl, M.-
dc.subjectLigação de hidrogêniopt_BR
dc.subjectFuncionais de densidadept_BR
dc.subjectAminoácidospt_BR
dc.subject.otherlanguageHydrogen bondingpt_BR
dc.subject.otherlanguageDensity functionalspt_BR
dc.subject.otherlanguageAminoacidspt_BR
dc.description.abstractThe conformational behaviour of Ac-Gly-NHMe in nonpolar, polar and polar protic solutions was systematically studied in this work by theoretical calculations and experimental infrared and H-1 NMR spectroscopies. Ac-Gly-NHMe prefers a gauche conformer with a strong seven-membered intramolecular hydrogen bond for the isolated compound and in nonpolar solvents, but such preference changes in polar and polar protic solvents. Elucidation of Ac-Gly-NHMe preferences was also supported by studying the conformers of its CF3-C(O)-Gly-NHMe and Ac-Gly-N(Me)(2) derivatives in solution.pt_BR
dc.relation.ispartofRSC advancespt_BR
dc.relation.ispartofabbreviationRSC adv.pt_BR
dc.publisher.cityCambridge, MApt_BR
dc.publisher.countryEstados Unidospt_BR
dc.publisherRoyal Society of Chemistrypt_BR
dc.date.issued2015-
dc.date.monthofcirculationJan.pt_BR
dc.language.isoengpt_BR
dc.description.volume5pt_BR
dc.description.issuenumber17pt_BR
dc.description.firstpage13052pt_BR
dc.description.lastpage13060pt_BR
dc.rightsAbertopt_BR
dc.sourceWOSpt_BR
dc.identifier.eissn2046-2069pt_BR
dc.identifier.doi10.1039/c4ra16472ept_BR
dc.identifier.urlhttps://pubs.rsc.org/en/content/articlelanding/2015/RA/C4RA16472Ept_BR
dc.description.sponsorshipCONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQpt_BR
dc.description.sponsorshipFUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESPpt_BR
dc.description.sponsordocumentnumbersem informaçãopt_BR
dc.description.sponsordocumentnumber2012/03933-5; 2011/01170-1pt_BR
dc.date.available2020-12-03T15:04:15Z-
dc.date.accessioned2020-12-03T15:04:15Z-
dc.description.provenanceSubmitted by Cintia Oliveira de Moura (cintiaom@unicamp.br) on 2020-12-03T15:04:15Z No. of bitstreams: 0. Added 1 bitstream(s) on 2021-02-19T19:00:26Z : No. of bitstreams: 1 000348987700072.pdf: 1436592 bytes, checksum: 680d6f8d1ca35375df9d5a0487c83cfc (MD5) Bitstreams deleted on 2021-02-19T19:07:52Z: 000348987700072.pdf,. Added 1 bitstream(s) on 2021-02-19T19:08:04Z : No. of bitstreams: 1 000348987700072.pdf: 1436592 bytes, checksum: 680d6f8d1ca35375df9d5a0487c83cfc (MD5)en
dc.description.provenanceMade available in DSpace on 2020-12-03T15:04:15Z (GMT). No. of bitstreams: 0 Previous issue date: 2015en
dc.identifier.urihttp://repositorio.unicamp.br/jspui/handle/REPOSIP/352957-
dc.contributor.departmentDepartamento de Química Orgânicapt_BR
dc.contributor.departmentDepartamento de Química Orgânicapt_BR
dc.contributor.unidadeInstituto de Químicapt_BR
dc.contributor.unidadeInstituto de Químicapt_BR
dc.subject.keywordHydration Waterpt_BR
dc.subject.keywordPolarized Ramanpt_BR
dc.identifier.source000348987700072pt_BR
dc.creator.orcid0000-0001-7659-1749pt_BR
dc.creator.orcid0000-0002-4715-6141pt_BR
dc.type.formArtigopt_BR
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