Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/350168
Type: Artigo
Title: Hydrogen peroxide electrogeneration in gas diffusion electrode nanostructured with Ta2O5
Author: Carneiro, Jussara F.
Rocha, Robson S.
Hammer, Peter
Bertazzoli, R.
Lanza, M.R.V.
Abstract: Highly efficient H2O2 electrogeneration is required in the Advanced Oxidation Process for organic wastewater treatment. However, the development of more efficient catalytic particles used in gas diffusion electrodes (GDEs) to enable the oxygen reduction reaction through two-electron transfer is still of great importance. The performance of the Ta2O5 nanoparticles on carbon black in catalyzing the ORR was evaluated using rotating ring-disk electrode. The current efficiency for H2O2 electrogeneration on Ta2O5/C catalyst is 83.2% whereas carbon black exhibits 65.3%. GDEs were constructed using carbon black either unmodified or modified with Ta2O5 nanoparticles. The modified GDE produces 27.9 mg L−1 of H2O2, while the unmodified GDE generates 19.1 mg L−1 of H2O2. Furthermore, the energy consumption for the H2O2 electrogeneration is lower in modified than in unmodified GDE (15.0 kW h vs. 18.8 kW h). The high performance of the GDE (Ta2O5/C) renders it a viable alternative cathode in the electrochemical treatment of wastewaters
Subject: Oxigênio
Peróxidos
Difusão
Hidrogênio
Country: Países Baixos
Editor: Elsevier
Rights: Fechado
Identifier DOI: 10.1016/j.apcata.2016.03.013
Address: https://www.sciencedirect.com/science/article/pii/S0926860X16301235
Date Issue: 2016
Appears in Collections:FEM - Artigos e Outros Documentos

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