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|Title:||Kinetic resolution of α-bromophenylacetamides using quinine or cinchona alkaloid salts|
Fejfar, José L.
Tormena, Claudio F.
Vitta, Claudio Di
|Abstract:||The kinetic resolution of racemic α-bromophenylacetamides 1 was achieved in the presence of benzenethiolate and Cinchona alkaloid salts as phase-transfer catalysts or benzenethiol and quinine, yielding (S)-enantioenriched α-sulfanylated products. The observed stereoselection was rationalized on the basis of the best fitting of 1 and the resolving agent in the ternary complexes|
|Appears in Collections:||IQ - Artigos e Outros Documentos|
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