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Type: Artigo
Title: Kinetic resolution of α-bromophenylacetamides using quinine or cinchona alkaloid salts
Author: Marzorati, Liliana
Fejfar, José L.
Tormena, Claudio F.
Vitta, Claudio Di
Abstract: The kinetic resolution of racemic α-bromophenylacetamides 1 was achieved in the presence of benzenethiolate and Cinchona alkaloid salts as phase-transfer catalysts or benzenethiol and quinine, yielding (S)-enantioenriched α-sulfanylated products. The observed stereoselection was rationalized on the basis of the best fitting of 1 and the resolving agent in the ternary complexes
Subject: Alcaloides
Country: Reino Unido
Editor: Elsevier
Rights: Fechado
Identifier DOI: 10.1016/j.tetasy.2012.05.009
Date Issue: 2012
Appears in Collections:IQ - Artigos e Outros Documentos

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