Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/345914
Type: Artigo
Title: Simulation of temperature effect on the structure control of polystyrene obtained by atom-transfer radical polymerization
Author: Vieira, Roniérik Pioli
Lona, Liliane Maria Ferrareso
Abstract: This paper uses a new kinetic modeling and simulations to analyse the effect of temperature on the polystyrene properties obtained by atom-transfer radical polymerization (ATRP). Differently from what has been traditionaly published in ATRP modeling works, it was considered “break” reactions in the mechanism aiming to reproduce the process at high temperatures. Results suggest that there is an upper limit temperature (130 °C), above which the polymer architecture loses the control. In addition, for the system considered in this work, the optimum operating temperature was 100 °C, because at this temperature polymer with very low polydispersity index is obtained, at considerable fast polymerization rate. Therefore, this present paper provides not only a tool to study ATRP processes by simulations, but also a tool for analysis and optimization, being a basis for future works dealing with this monomer and process
Subject: Polimerização
Country: Brasil
Editor: Associação Brasileira de Polimeros
Rights: Aberto
Identifier DOI: 10.1590/0104-1428.2376
Address: https://www.scielo.br/scielo.php?script=sci_arttext&pid=S0104-14282016000400313
Date Issue: 2016
Appears in Collections:FEQ - Artigos e Outros Documentos

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