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Type: Artigo
Title: Liquid-liquid equilibrium in systems used for the production of 5-hydroxymethylfurfural from biomass using alcohols as solvents
Author: Dalmolin, Irede
Pinto, Rafaela R.
Oliveira, Leonardo H. de
Follegatti-Romero, Luis A.
Costa, Aline C.
Aznara, Martín
Abstract: The present work reports liquid–liquid equilibrium data for systems containing water + 5-hydroxymethylfurfural + {1-butanol, 2-butanol or 2-pentanol} at T = 298.2 K and atmospheric pressure (∼0.1 MPa), determined by refractometry and density measurements. The results were evaluated by calculation of the overall mass balance, resulting in overall relative deviations lower than 1.05%. Experimental data were correlated with the NRTL model to calculate the activity coefficient. The average root mean square deviation was equal to 0.65% for all systems. Cloud points, tie lines, partition coefficients and selectivities indicated that 2-pentanol is better than the other studied solvents for 5-hydroxymethylfurfural recovery from water
Subject: Equilíbrio líquido-líquido
Country: Reino Unido
Editor: Elsevier
Rights: Fechado
Identifier DOI: 10.1016/j.jct.2017.03.019
Date Issue: 2017
Appears in Collections:FEQ - Artigos e Outros Documentos

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