Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/343176
Type: Artigo
Title: Hydrothermal synthesis to water-stable luminescent carbon dots from acerola fruit for photoluminescent composites preparation and its application as sensors
Author: Carvalho, J.
Santos, L.R.
Germino, J.C.
Terezo, A.J.
Moreto, J.A.
Quites, F.J.
Freitas, R.G.
Abstract: Carbon dots (C-dots) possess the attractive properties of high stability, low toxicity, good water solubility, simple synthetic routes as well as size and excitation-dependent photoluminescence (PL).The aim of this work was to synthesize photoluminescent C-dots by hydrothermal method using acerola fruit (Malpighiaemarginata) as a row material, since this fruit contains large number of organic molecules. Studies about the optimal synthesis conditions were performed, where these organic molecules were converted into C-dots by hydrothermal carbonization at 180 ºC for 18 h. The C-dots exhibited a green emission light at 459 nm when excited under UV-light (λ ex= 370 nm). These nanomaterials were also successfully used to prepare C-dots/poly (vinyl alcohol) luminescent composites (C-dots/PVA). Both C-dots and C-dots/PVA composite films were investigated by using colorimetric visual sensor for Fe3+ metal ions detection. The results show that the prepared C-dots and C-dots/poly presented strong green emission light. The emission spectra of above materials were quenched in the presence of Fe3+ ions. Thus, highly specific “turn off” fluorescence sensing of Fe3+ was achieved using fluorescent C-dots. Regarding, this work describe that the polymeric films as sensors of metallic ions in aqueous solution appears as a new perspectives to design new composite materials
Subject: Carbono
Country: Brasil
Editor: UFSCar/Departamento de Engenharia de Materiais
Rights: Aberto
Identifier DOI: 10.1590/1980-5373-MR-2018-0920
Address: https://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392019000300238
Date Issue: 2019
Appears in Collections:IQ - Artigos e Outros Documentos

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