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Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/341403
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dc.contributor.CRUESPUNIVERSIDADE ESTADUAL DE CAMPINASpt_BR
dc.contributor.authorunicampRossini, Allan Felipe da Costa-
dc.contributor.authorunicampDias, Luiz Carlos-
dc.typeArtigopt_BR
dc.titleSynthesis of the C(7)-C(20) fragment of spirotoamides A, B and Cpt_BR
dc.contributor.authorRossini, Allan F. C.-
dc.contributor.authorDias, Luiz C.-
dc.subjectProdutos biológicospt_BR
dc.subjectReação aldólicapt_BR
dc.subject.otherlanguageBiological productspt_BR
dc.subject.otherlanguageAldol reactionpt_BR
dc.description.abstractThis work describes the preparation of the C(7)-C(20) fragment of spirotoamides A to C in a very elegant fashion, achievement very high levels of stereocontrol. The synthesis has been accomplished by a sequence involving 14 steps (0.36% overall yield, average of 81% for each step) in high diastereo and enantioselectivity, employing, as determining steps, asymmetric Mukaiyama and boron-mediated 1,5-anti promoted aldol reactions between alpha-methyl-beta-hydroxyketones and aldehydespt_BR
dc.relation.ispartofJournal of the Brazilian Chemical Societypt_BR
dc.relation.ispartofabbreviationJ. Braz. Chem. Soc.pt_BR
dc.publisher.citySão Paulo, SPpt_BR
dc.publisher.countryBrasilpt_BR
dc.publisherSociedade Brasileira de Químicapt_BR
dc.date.issued2019-
dc.date.monthofcirculationAug.pt_BR
dc.language.isoengpt_BR
dc.description.volume30pt_BR
dc.description.issuenumber8pt_BR
dc.description.firstpage1567pt_BR
dc.description.lastpage1578pt_BR
dc.rightsAbertopt_BR
dc.sourceSCiELOpt_BR
dc.identifier.issn0103-5053pt_BR
dc.identifier.eissn1678-4790pt_BR
dc.identifier.doi10.21577/0103-5053.20190126pt_BR
dc.identifier.urlhttps://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532019000801567pt_BR
dc.description.sponsorshipCONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQpt_BR
dc.description.sponsorshipFUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESPpt_BR
dc.description.sponsordocumentnumber160646/2014-6pt_BR
dc.description.sponsordocumentnumber2015/50655-9pt_BR
dc.date.available2020-05-14T14:55:54Z-
dc.date.accessioned2020-05-14T14:55:54Z-
dc.description.provenanceSubmitted by Cintia Oliveira de Moura (cintiaom@unicamp.br) on 2020-05-14T14:55:54Z No. of bitstreams: 0. Added 1 bitstream(s) on 2020-08-27T19:16:05Z : No. of bitstreams: 1 S0103-50532019000801567.pdf: 654221 bytes, checksum: 616becf8a82c9ce4f603fcd3b8a76cd6 (MD5)en
dc.description.provenanceMade available in DSpace on 2020-05-14T14:55:54Z (GMT). No. of bitstreams: 0 Previous issue date: 2019en
dc.identifier.urihttp://repositorio.unicamp.br/jspui/handle/REPOSIP/341403-
dc.contributor.departmentsem informaçãopt_BR
dc.contributor.departmentDepartamento de Química Orgânicapt_BR
dc.contributor.unidadeInstituto de Químicapt_BR
dc.contributor.unidadeInstituto de Químicapt_BR
dc.subject.keywordMukaiyama reactionpt_BR
dc.subject.keywordSpirotoamidespt_BR
dc.identifier.sourceS0103-50532019000801567pt_BR
dc.creator.orcidsem informaçãopt_BR
dc.creator.orcid0000-0003-0628-9928pt_BR
dc.type.formComunicaçãopt_BR
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