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|Title:||Continuous flow processing as a tool for the generation of terpene-derived monomer libraries|
Fernandes, Lucas P.
Browne, Duncan L.
Pastre, Julio C.
|Abstract:||We report the development of a continuous flow approach for the preparation of two bio-derived monomer libraries. A small range of terpenes (ocimene, myrcene, -terpinene, -phellandrene, isoprene, and farnesene) have been used as the base set for the library, with the first library derived from a Diels-Alder reaction with the platform chemical maleic anhydride. The second library requires the derivatization of the first through a hydrogenation reaction. The potential for scale-up of both libraries has been demonstrated, with the Diels-Alder process delivering 10.5 grams of the product in 3 hours and the hydrogenation process delivering 10 grams of the material in 16 hours|
|Editor:||Royal Society of Chemistry|
|Appears in Collections:||IQ - Artigos e Outros Documentos|
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