Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/337050
Type: Artigo
Title: Development of novel sericin and alginate-based biosorbents for precious metal removal from wastewater
Author: das Gracas Santos, Nilza Tatiane
Carlos da Silva, Meuris Gurgel
Adeodato Vieira, Melissa Gurgel
Abstract: In this study, two novel low water-soluble sericin and alginate-based biosorbents were successfully developed for precious metal removal from wastewater: sericin and alginate particles chemically crosslinked by proantocyanidins (SAPAs) and sericin, alginate and polyvinyl alcohol particles (SAPVA). The proportions of proantocynidins (PAs) or polyvinyl alcohol (PVA) added to sericin (2.5% w/v) and alginate (2.0% w/v) blend were 0.5, 1.5, 2.5 and 3.5% w/v. Among these concentrations, particles produced with 0.5% w/v of PVA or 2.5% w/v of PAs presented the lowest water solubility percentages (3.74 +/- 0.05 and 3.56 +/- 0.21%, respectively) and the following metallic affinity order: AuCl4- > PdCl42- > PtCl62-> Ag+. Then, gold biosorption kinetics by SAPAs was evaluated at three gold initial concentrations (72.88, 187.12, and 273.79 mg/L), and its performance was compared to activated carbon adsorbent uptake. The data modeling revealed that the process follows pseudo-first-order kinetics and is mainly controlled by external diffusion. SAPAs before and after gold biosorption (SAPAs-gold) were characterized by scanning electron microscopy coupled with energy dispersive X-ray spectroscopy, optical microscopy, helium pycnometry, mercury porosimetry, N-2 physisorption, and Fourier-transform infrared spectroscopy
Subject: Metais preciosos
Poli (álcool vinílico)
Proantocianidinas
Country: Alemanha
Editor: Springer
Rights: Fechado
Identifier DOI: 10.1007/s11356-018-3378-z
Address: https://link.springer.com/article/10.1007/s11356-018-3378-z
Date Issue: 2019
Appears in Collections:IQ - Artigos e Outros Documentos

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