Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/330178
Type: Artigo
Title: Perovskite-inspired Photovoltaic Materials: Toward Best Practices In Materials Characterization And Calculations
Author: Hoye
Robert L. Z.; Schulz
Philip; Schelhas
Laura T.; Holder
Aaron M.; Stone
Kevin H.; Perkins
John D.; Vigil-Fowler
Derek; Siol
Sebastian; Scanlon
David O.; Zakutayev
Andriy; Walsh
Aron; Smith
Ian C.; Melot
Brent C.; Kurchin
Rachel C.; Wang
Yiping; Shi
Jian; Marques
Francisco C.; Berry
Joseph J.; Tumas
William; Lany
Stephan; Stevanovic
Vladan; Toney
Michael F.; Buonassisi
Tonio
Abstract: Recently, there has been an explosive growth in research based on hybrid lead halide perovskites for photovoltaics 3 owing to rapid improvements in efficiency. The advent of these "materials for solar applications has led to widespread interest in understanding the key enabling properties of these materials. This has resulted in renewed interest in related compounds and a search for materials that may replicate the defect-tolerant properties and long lifetimes of the hybrid lead-halide perovskites. Given the rapid pace of development of the field, the rises in efficiencies of these systems have outpaced the more basic understanding of these materials. Measuring or calculating the basic properties, such as crystal/electronic structure and composition, can be challenging because some of these materials have anisotropic structures, and/or are composed of both heavy metal cations and volatile, mobile, light elements. Some consequences are beam damage during characterization, composition change under vacuum, or compound effects, such as the alteration of the electronic structure through the influence of the substrate. These effects make it challenging to understand the basic properties integral to optoelectronic operation. Compounding these difficulties is the rapid pace with which the field progresses. This has created an ongoing need to continually evaluate best practices with respect to characterization and calculations, as well as to identify inconsistencies in reported values to determine if those inconsistencies are rooted in characterization methodology or materials synthesis. This article describes the difficulties in characterizing hybrid lead halide perovskites and new materials and how these challenges may be overcome. The topic was discussed at a seminar at the 2015 Materials Research Society Fall Meeting & Exhibit. This article highlights the lessons learned from the seminar and the insights of some of the attendees, with reference to both recent literature and controlled experiments to illustrate the challenges discussed. The focus in this article is on crystallography, composition measurements, photoemission spectroscopy, and calculations on perovskites and new, related absorbers. We suggest how the reporting of the important artifacts could be streamlined between groups to ensure reproducibility as the field progresses.
Editor: Amer Chemical Soc
Washington
Rights: fechado
Identifier DOI: 10.1021/acs.chemmater.6b03852
Address: http://pubs.acs.org/doi/abs/10.1021/acs.chemmater.6b03852
Date Issue: 2017
Appears in Collections:Unicamp - Artigos e Outros Documentos

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