Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/330029
Type: Artigo
Title: Tuning The Emission Color Of A Single-layer Polymer Light-emitting Diode With A Solution-processed External Layer
Author: de Azevedo
Diego; Freitas
Jilian Nei; Domingues
Raquel Aparecida; Faleiros
Marcelo Meira; de Almeida Santos
Thebano Emilio; Zambon Atvars
Teresa Dib
Abstract: The emission color of a single-layer polymer light-emitting diode (PLED) was tuned using an external layer. We combine an electroluminescent polymer, known as poly[(9,9-dioctylfluoreny1-2,7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,8-diy1)] (F8BT), embedded in a diode-like structure (ITO/PEDOT-PPS/F8BT/Ca/Al), and a film of poly(vinyl alcohol) (PVA) containing one of the xanthene dyes, either Erythrosin B (ERB) or Rose Bengal (RB), used as an external photoluminescent layer. The emission color is tuned from the CIE coordinates (034, 0.64) for the bare F8BT-diode to (0.39, 0,57) using a similar to 42 mu m PVA:RB film and to (035, 0.61) using a similar to 55 mu m PVA:ERB film. It was obtained based on trivial photophysical processes: xanthene dyes partially absorb the electroluminescence (EL) emissions coming from the F8BT-diode, decaying radiatively and emitting light by photoluminescence (PL). This method is versatile and may be extended to other combinations of EL and PL materials, tuning the color output and giving different CIE color coordinates. Because both the EL and PL layers are polymer-based systems, they can be used in the development of flexible displays and illumination sources. Furthermore, the PL layer is a self-supported film formed by water-soluble materials, with the advantage of being environmentally friendly, commercially available and low-cost. The PLED delivered a brightness of 123 cd/m(2) at 9 V. (C) 2016 Elsevier B.V. All rights reserved.
Subject: Photoluminescence
Electroluminescence
Xanthene Dyes
Polyfluorenes
Color Tuning
Editor: Elsevier Science SA
Lausanne
Rights: fechado
Identifier DOI: 10.1016/j.synthmet.2016.10.024
Address: http://www.sciencedirect.com/science/article/pii/S037967791630354X
Date Issue: 2016
Appears in Collections:Unicamp - Artigos e Outros Documentos

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