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dc.contributor.CRUESPUNIVERSIDADE ESTADUAL DE CAMPINASpt_BR
dc.contributor.authorunicampHorner, Annapt_BR
dc.contributor.authorunicampCastañeda Tutestar, Juan Andréspt_BR
dc.contributor.authorunicampFerencz Júnior, Julio Alberto Perespt_BR
dc.contributor.authorunicampPadilha Junior, Lázaro Auréliopt_BR
dc.typeArtigopt_BR
dc.titleLinear And Nonlinear Optical Spectroscopy Of Fluoroalkylated Bodipy Dyesen
dc.titleLinear and nonlinear optical spectroscopy of fluoroalkylated BODIPY dyespt_BR
dc.contributor.authorKölmel, D. K.pt_BR
dc.contributor.authorHörner, A.pt_BR
dc.contributor.authorCastañeda, J. A.pt_BR
dc.contributor.authorFerencz, J. A. P.pt_BR
dc.contributor.authorBihlmeier, A.pt_BR
dc.contributor.authorNieger, M.pt_BR
dc.contributor.authorBräse, S.pt_BR
dc.contributor.authorPadilha, L. A.pt_BR
dc.subjectÓtica não-linear, Química quântica, Espectroscopia óticapt_BR
dc.subject.otherlanguageNonlinear optics, Quantum chemistry, Optical spectroscopypt_BR
dc.description.abstractA series of fluoroalkyl-labeled BODIPY dyes have been synthesized with different substituents on the 2- and 6-positions and investigated in terms of their spectroscopic properties. The dyes were decorated with aryl, alkenyl, and alkynyl substituents, respectively. Those substituents are able to expend the dyes' delocalized pi-electron system to different extents. Detailed linear and nonlinear optical spectroscopy methods as well as quantum-chemical calculations have been employed to verify the influence of those different substituents on the electronic distribution and, ultimately, on the molecules' optical properties. From the nonlinear optical measurements, we find that the substituents highly influence the excited-state absorption properties, which could be tuned in wavelength by similar to 100 nm and in magnitude by over 1 order of magnitude, reaching peak values close to 10(-15) cm(2) for one of the alkynyl-containing dyes.en
dc.description.abstractA series of fluoroalkyl-labeled BODIPY dyes have been synthesized with different substituents on the 2- and 6-positions and investigated in terms of their spectroscopic properties. The dyes were decorated with aryl, alkenyl, and alkynyl substituents, respectively. Those substituents are able to expend the dyes' delocalized pi-electron system to different extents. Detailed linear and nonlinear optical spectroscopy methods as well as quantum-chemical calculations have been employed to verify the influence of those different substituents on the electronic distribution and, ultimately, on the molecules' optical properties. From the nonlinear optical measurements, we find that the substituents highly influence the excited-state absorption properties, which could be tuned in wavelength by similar to 100 nm and in magnitude by over 1 order of magnitude, reaching peak values close to 10(-15) cm(2) for one of the alkynyl-containing dyes.pt_BR
dc.relation.ispartofThe journal of physical chemistry. Part Cpt_BR
dc.relation.ispartofabbreviationJ. phys. chem. Cpt_BR
dc.publisher.cityWashington, WApt_BR
dc.publisher.countryEstados Unidospt_BR
dc.publisherAmerican Chemical Societypt_BR
dc.date.issued2016pt_BR
dc.date.monthofcirculationMar.pt_BR
dc.identifier.citationJournal Of Physical Chemistry C. Amer Chemical Soc, v. 120, p. 4538 - 4545, 2016.pt_BR
dc.language.isoengpt_BR
dc.description.volume120pt_BR
dc.description.issuenumber8pt_BR
dc.description.firstpage4538pt_BR
dc.description.lastpage4545pt_BR
dc.rightsfechadopt_BR
dc.sourceWOSpt_BR
dc.identifier.issn1932-7447pt_BR
dc.identifier.eissn1932-7455pt_BR
dc.identifier.doi10.1021/acs.jpcc.6b00096pt_BR
dc.identifier.urlhttps://pubs.acs.org/doi/10.1021/acs.jpcc.6b00096pt_BR
dc.description.sponsorshipCAPES - COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIORpt_BR
dc.description.sponsorshipCNPQ - CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICOpt_BR
dc.description.sponsorshipFAPESP - FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULOpt_BR
dc.description.sponsorship1CAPES - COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIORpt_BR
dc.description.sponsorship1CNPQ - CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICOpt_BR
dc.description.sponsorship1FAPESP - FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULOpt_BR
dc.description.sponsordocumentnumberSem informaçãopt_BR
dc.description.sponsordocumentnumberSem informaçãopt_BR
dc.description.sponsordocumentnumber2013/16911-2pt_BR
dc.date.available2017-11-13T13:51:01Z-
dc.date.accessioned2017-11-13T13:51:01Z-
dc.description.provenanceMade available in DSpace on 2017-11-13T13:51:01Z (GMT). No. of bitstreams: 1 000371562000043.pdf: 1335118 bytes, checksum: e8ffb178c36b1ef4ea5d14144c75c3c7 (MD5) Previous issue date: 2016 Bitstreams deleted on 2020-09-02T13:43:09Z: 000371562000043.pdf,. Added 1 bitstream(s) on 2020-09-02T13:47:35Z : No. of bitstreams: 1 000371562000043.pdf: 1425777 bytes, checksum: 4b735c88ee3d7810805dbe2af1b383ef (MD5)en
dc.identifier.urihttp://repositorio.unicamp.br/jspui/handle/REPOSIP/329320-
dc.contributor.departmentDepartamento de Eletrônica Quânticapt_BR
dc.contributor.departmentDepartamento de Eletrônica Quânticapt_BR
dc.contributor.departmentDepartamento de Eletrônica Quânticapt_BR
dc.contributor.departmentDepartamento de Eletrônica Quânticapt_BR
dc.contributor.unidadeInstituto de Física Gleb Wataghinpt_BR
dc.contributor.unidadeInstituto de Física Gleb Wataghinpt_BR
dc.contributor.unidadeInstituto de Física Gleb Wataghinpt_BR
dc.contributor.unidadeInstituto de Física Gleb Wataghinpt_BR
dc.identifier.source000371562000043pt_BR
dc.creator.orcidSem informaçãopt_BR
dc.creator.orcid0000-0003-0906-0037pt_BR
dc.creator.orcid0000-0002-6164-2213pt_BR
dc.creator.orcid0000-0002-8825-6611pt_BR
dc.type.formArtigopt_BR
dc.description.sponsorNoteThe Chemical Industry Fund (fellowship to D.K.K.), the Karlsruhe School of Optics & Photonics (fellowship to D.K.K. and A.H.), the Carl Zeiss Foundation (fellowship to A.H.), and the Karlsruhe House of Young Scientists (KHYS, fellowship abroad A.H.) are acknowledged. We acknowledge support from the Deutsche Forschungsgemeinschaft through GRK 2165 and SFB 1176 (project A4 of S.B. and project Q4 of A.B.). J.A.C. and J.A.P.F acknowledge CAPES and CNPQ–Brazilian Funding Agencies for their scholarship, and L.A.P. acknowledges funding from the Sao Paulo State Funding Agency (FAPESP) under the grant 2013/16911-2.pt_BR
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