Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/329320
Type: Artigo
Title: Linear And Nonlinear Optical Spectroscopy Of Fluoroalkylated Bodipy Dyes
Linear and nonlinear optical spectroscopy of fluoroalkylated BODIPY dyes
Author: Kölmel, D. K.
Hörner, A.
Castañeda, J. A.
Ferencz, J. A. P.
Bihlmeier, A.
Nieger, M.
Bräse, S.
Padilha, L. A.
Abstract: A series of fluoroalkyl-labeled BODIPY dyes have been synthesized with different substituents on the 2- and 6-positions and investigated in terms of their spectroscopic properties. The dyes were decorated with aryl, alkenyl, and alkynyl substituents, respectively. Those substituents are able to expend the dyes' delocalized pi-electron system to different extents. Detailed linear and nonlinear optical spectroscopy methods as well as quantum-chemical calculations have been employed to verify the influence of those different substituents on the electronic distribution and, ultimately, on the molecules' optical properties. From the nonlinear optical measurements, we find that the substituents highly influence the excited-state absorption properties, which could be tuned in wavelength by similar to 100 nm and in magnitude by over 1 order of magnitude, reaching peak values close to 10(-15) cm(2) for one of the alkynyl-containing dyes.
A series of fluoroalkyl-labeled BODIPY dyes have been synthesized with different substituents on the 2- and 6-positions and investigated in terms of their spectroscopic properties. The dyes were decorated with aryl, alkenyl, and alkynyl substituents, respectively. Those substituents are able to expend the dyes' delocalized pi-electron system to different extents. Detailed linear and nonlinear optical spectroscopy methods as well as quantum-chemical calculations have been employed to verify the influence of those different substituents on the electronic distribution and, ultimately, on the molecules' optical properties. From the nonlinear optical measurements, we find that the substituents highly influence the excited-state absorption properties, which could be tuned in wavelength by similar to 100 nm and in magnitude by over 1 order of magnitude, reaching peak values close to 10(-15) cm(2) for one of the alkynyl-containing dyes.
Subject: Ótica não-linear, Química quântica, Espectroscopia ótica
Country: Estados Unidos
Editor: American Chemical Society
Citation: Journal Of Physical Chemistry C. Amer Chemical Soc, v. 120, p. 4538 - 4545, 2016.
Rights: fechado
Identifier DOI: 10.1021/acs.jpcc.6b00096
Address: https://pubs.acs.org/doi/10.1021/acs.jpcc.6b00096
Date Issue: 2016
Appears in Collections:IFGW - Artigos e Outros Documentos

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