Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/328973
Type: Artigo
Title: Supercritical Co2 Extraction As A Selective Method For The Obtainment Of Coumarins From Pterocaulon Balansae (asteraceae)
Author: Torres
Fernando Cidade; Medeiros-Neves
Bruna; Teixeira
Helder Ferreira; Kawanoa
Daniel; Eifler-Lima
Vera Lucia; Cassel
Eduardo; Figueiro Vargas
Rubem Mario; von Poser
Gilsane Lino
Abstract: Aiming to recover fractions enriched with coumarins, the aerial parts of Pterocaulon balansae Chodat (Asteraceae) were subjected to supercritical fluid extraction (SFE) using CO2 as solvent under constant temperature (40 degrees C) and gradual pressure increments (90, 120, 150 and 200 bar). The yields of the coumarins in the extracts were calculated using high-performance liquid chromatography analyses, which allowed the identification of seven coumarins previously reported by our research group. Coumarin 7-((3,3-dimethyloxiran-2-yl) methoxy)-5,6-dimethoxy-2H-chromen-2-one was identified as the major component of all extracts but we also identified considerable amounts of other epoxysubstituted coumarins. The mild conditions provided by the supercritical CO2 extraction (SC-CO2 extraction) may considerably reduce the ring-opening of the epoxy groups in the coumarins from the aerial parts of P. balansae, when compared to the conventional extraction procedures. (C) 2017 Elsevier Ltd. All rights reserved.
Subject: Pterocaulon Balansae
Coumarins
Supercritical Fluid Extraction
Carbon Dioxide
Epoxy-coumarins
Editor: Elsevier Science Ltd
Oxford
Rights: fechado
Identifier DOI: 10.1016/j.jcou.2017.02.008
Address: http://www.sciencedirect.com/science/article/pii/S221298201630107X
Date Issue: 2017
Appears in Collections:Unicamp - Artigos e Outros Documentos

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