Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/327478
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dc.contributor.CRUESPUNIVERSIDADE ESTADUAL DE CAMPINASpt_BR
dc.contributor.authoremailtormena@iqm.unicamp.br; bo.xu@dhu.edu.cn; gb.hammond@louisville.edupt_BR
dc.typeArtigopt_BR
dc.titleAchieving Regio- And Stereo-control In The Fluorination Of Aziridines Under Acidic Conditionsen
dc.titleAchieving regio- and stereo-control in the fluorination of aziridines under acidic conditionspt_BR
dc.contributor.authorOkoromoba, Otome E.pt_BR
dc.contributor.authorLi, Zhoupt_BR
dc.contributor.authorRobertson, Nicolept_BR
dc.contributor.authorMashuta, Mark S.pt_BR
dc.contributor.authorCouto, Uenifer R.pt_BR
dc.contributor.authorTormena, Cláudio F.pt_BR
dc.contributor.authorXu, Bopt_BR
dc.contributor.authorHammond, Gerald B.pt_BR
unicamp.authorTormena, Claudio F.] Univ Estadual Campinas, Inst Chem, BR-13083970 Sao Paulo, Brazilpt_BR
unicamp.author.external[Okoromoba, Otome E.pt_BR
unicamp.author.externalLi, Zhoupt_BR
unicamp.author.externalRobertson, Nicolept_BR
unicamp.author.externalMashuta, Mark S.pt_BR
unicamp.author.externalHammond, Gerald B.] Univ Louisville, Dept Chem, Louisville, KY 40292 USApt_BR
unicamp.author.external[Couto, Uenifer R.pt_BR
unicamp.author.external[Xu, Bo] Donghua Univ, Coll Chem Chem Engn & Biotechnol, 2999 North Renmin Lu, Shanghai 201620, Peoples R Chinapt_BR
dc.subjectHydrogen-fluorideen
dc.subjectSynthetic Methodsen
dc.subjectAminesen
dc.subjectReagentsen
dc.subjectHydrofluorinationen
dc.subjectDerivativesen
dc.subjectConvenienten
dc.subjectComplexesen
dc.subjectCatalysisen
dc.subjectAlkynesen
dc.subjectAziridinapt_BR
dc.subjectFluoraçãopt_BR
dc.subject.otherlanguageAziridinespt_BR
dc.subject.otherlanguageFluorinationpt_BR
dc.description.abstractWe developed an efficient fluorination protocol that converts easily accessible aziridines into beta-fluoroamines, which are important motifs in biologically active molecules. In contrast with traditional fluorination approaches, DMPU-HF has shown both higher reactivity and regioselectivity and good functional group tolerance; thus, a wide scope of beta-fluoroamines can now be accessed conveniently. The stereochemical behavior of the ring opening depends on the substitution pattern of the aziridine substrate.en
dc.description.abstractWe developed an efficient fluorination protocol that converts easily accessible aziridines into β-fluoroamines, which are important motifs in biologically active molecules. In contrast with traditional fluorination approaches, DMPU–HF has shown both highept_BR
dc.relation.ispartofChemical communicationspt_BR
dc.relation.ispartofabbreviationChem. commun.pt_BR
dc.publisher.cityCambridgept_BR
dc.publisher.countryReino Unidopt_BR
dc.publisherRoyal Society of Chemistrypt_BR
dc.date.issued2016pt_BR
dc.date.monthofcirculationOct.pt_BR
dc.identifier.citationChemical Communications. Royal Soc Chemistry, v. 52, p. 13353 - 13356, 2016.pt_BR
dc.language.isoengpt_BR
dc.description.volume52pt_BR
dc.description.issuenumber91pt_BR
dc.description.firstpage13353pt_BR
dc.description.lastpage13356pt_BR
dc.rightsfechadopt_BR
dc.sourceWOSpt_BR
dc.identifier.issn1359-7345pt_BR
dc.identifier.eissn1364-548Xpt_BR
dc.identifier.wosidWOS:000388102800007pt_BR
dc.identifier.doi10.1039/C6CC07855Apt_BR
dc.identifier.urlhttps://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC07855A#!divAbstractpt_BR
dc.description.sponsorshipNational Institutes of Health [R15 GM101604-01]pt_BR
dc.description.sponsorshipNational Science Foundation [CHE-1401700]pt_BR
dc.description.sponsorshipNational Science Foundation of China [NSFC-21472018]pt_BR
dc.description.sponsorshipSao Paulo Research Foundation (FAPESP) [2015/08541-6]pt_BR
dc.description.sponsorship1Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)pt_BR
dc.date.available2017-11-13T13:16:04Z-
dc.date.accessioned2017-11-13T13:16:04Z-
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dc.identifier.urihttp://repositorio.unicamp.br/jspui/handle/REPOSIP/327478-
dc.type.formArtigopt_BR
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