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Type: Artigo de Periódico
Title: Influence Of Pore Former And Transition Metal On Development Of Nanophases In Porous Silicon Oxycarbide (sico) Ceramics Obtained By Catalyst-assisted Pyrolysis
Author: Pereira
JL; de Oliveira
CS; Tarley
CRT; Mazali
IO; Segatelli
Abstract: This study describes the simultaneous formation of graphitic carbon nanostructures in combination with nanowires and crystallites based on silicon carbide (SiC) on porous Co-modified silicon oxycarbide (SiCO) ceramics derived from polymeric precursors. Polyethylene (PE)-containing polymers with and without cobalt acetate, Co(Ac)(2), were prepared by hydrosylilation reaction between 2,4,6,8-tetramethylcyclotetrasiloxane and divinylbenzene followed by pyrolysis at 1000 and 1500 degrees C to obtain the corresponding porous ceramic materials. The presence of Co(Ac)2 promoted the formation of conducting and semiconducting phases of graphitic carbon and SiC and this tendency was intensified by the simultaneous presence of PE and Co(Ac)(2) at 1500 degrees C. The production of SiC nanowires seems to be originated from their crystallites initially formed into matrix. However, their pronounced development was dependent on reductive atmosphere mainly generated by PE degradation. The presented approach and selected starting materials showed to be desirable to obtain SiCO-based ceramics with potential for new electrical applications. (C) 2016 Elsevier Ltd. All rights reserved.
Subject: Sico Ceramic
Graphitic Carbon
Sic Nanostructures
Pore Former
Rights: fechado
Identifier DOI: 10.1016/j.jeurceramsoc.2016.01.013
Date Issue: 2016
Appears in Collections:Unicamp - Artigos e Outros Documentos

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