Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/319397
Type: Artigo de periódico
Title: Electron Collisions With Small Esters: A Joint Experimental-theoretical Investigation
Abstract: A theoretical and experimental investigation on elastic electron scattering by two small esters, namely, methyl formate and ethyl acetate, is reported. Experimental differential, integral, and momentum-transfer cross sections are given in the 30-1000 eV and 10-120 ranges. The relative-flow technique was used to determine such quantities. Particularly for methyl formate, a theoretical study was also carried out in the 1-500 eV range. A complex optical potential derived from a Hartree-Fock molecular wave function was used to represent the collision dynamics, whereas the Padé approximation was used to solve the scattering equations. In addition, calculations based on the framework of the independent-atom model (IAM) were also performed for both targets. In general, there is good agreement between our experimental data and the present theoretical results calculated using the Padé approximation. The theoretical results using the IAM also agree well with the experimental data at 200 eV and above. Moreover, for methyl formate, our calculations reveal a 2A′′ (π∗) resonance at about 3.0 eV and a σ∗-type resonance centered at about 8.0 eV in the 2A′ scattering channel. The π∗ resonance is also seen in other targets containing a carbonyl group. © 2016 American Physical Society.
Editor: American Physical Society
Citation: Physical Review A - Atomic, Molecular, And Optical Physics. American Physical Society, v. 93, p. , 2016.
Rights: aberto
Identifier DOI: 10.1103/PhysRevA.93.032711
Address: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84963684434&partnerID=40&md5=d066adbb5129ce6b99db07f29ff95318
Date Issue: 2016
Appears in Collections:Unicamp - Artigos e Outros Documentos

Files in This Item:
There are no files associated with this item.


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.