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Type: Artigo de periódico
Title: Study of Co2+ in different crystal field environments
Author: Foglio, M. E.
Barberis, G. E.
Abstract: We consider the ESR of Co2+ in different environments: in an regular octahedron (Co2+ in a MgO crystal), in a deformed octahedron (Co2+ in single crystals and powder samples of NH4NiPO4.6H2O) or in a trigonal bipyramid (Co2+ in powders of Co2(OH)PO4 and Co2(OH)AsO4). We study the effect of the non-cubic crystal fields in the ESR of Co2+ in the deformed octahedron, by employing the normal modes of this structure to simplify the systematic study of the effect of these fields. A similar study was done for the deformed trigonal bipiramid, and it was necessary to derive the normal modes of this complex that are relevant to our problem.
Subject: ESR
Crystal field
Editor: Sociedade Brasileira de Física
Rights: aberto
Identifier DOI: 10.1590/S0103-97332006000100010
Date Issue: 1-Mar-2006
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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