Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/244168
Type: Artigo de periódico
Title: Comprehensive Characterization Of Second-generation Biofuel From Invasive Freshwater Plants By Ft-icr Ms
Author: Santos
Jandyson M.; dos Santos
Luana O.; Silva
Fernanda F.; Eberlin
Marcos N.; Wisniewski
Alberto
Jr.
Abstract: Ultra-high resolution and mass accuracy Fourier transform-ion cyclotron resonance mass spectrometry (FT-ICR MS) with an electrospray ionization source (ESI) was applied to characterize the bio-oils that were obtained using a micropyrolysis process of alternative biomasses from Eichornia crassipes (water hyacinth), Eichornia azurea, and Nymphaea ssp. The methods that have been developed for petroleomic analyses using FT-ICR MS data from crude oils and derivatives have been successfully employed herein to process such data for bio-oils, which are known as second-generation liquid biofuels. Class distributions and DBE versus carbon number plots (DBE x Cn) were, therefore, obtained. The class distribution for the oil obtained from water hyacinth was similar to those of classical bio-oils and appeared to be applicable as a fingerprint for bio-oils in general. The N-2 and O-2 classes obtained via ESI(+) and the O-2 and O-3 classes obtained via ESI(-) were the major classes detected in the bio-oil samples. In the DBE x Cn plot of the ESI(-)-FT-ICR MS data, the distribution of saturated and unsaturated fatty acids could be visualized, and characteristic profiles were determined for each bio-oil. It is, therefore, demonstrated that the FT-ICR MS methodology that is commonly applied to petroleomic studies can also be applied to biofuel characterization in a comprehensive "bio-oilomics" approach.
Subject: Resonance Mass-spectrometry
Bio-oil
Thermochemical Conversion
Fast Pyrolysis
Hyacinth
Petroleomics
Liquefaction
Biomass
Country: NEW YORK
Editor: SPRINGER
Citation: Comprehensive Characterization Of Second-generation Biofuel From Invasive Freshwater Plants By Ft-icr Ms. Springer, v. 8, p. 1938-1945 DEC-2015.
Rights: fechado
Identifier DOI: 10.1007/s12155-015-9650-x
Address: http://link.springer.com/article/10.1007%2Fs12155-015-9650-x#page-1
Date Issue: 2015
Appears in Collections:Unicamp - Artigos e Outros Documentos

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