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dc.contributor.CRUESPUNIVERSIDADE DE ESTADUAL DE CAMPINASpt_BR
dc.typeArtigo de periódicopt_BR
dc.titlePhotostable, Oxygen-sensitive Optical Probe Based On A Homonuclear Terbium(iii) Complex Covalently Bound To Functionalized Polydimethylsiloxanept_BR
dc.contributor.authorGasparpt_BR
dc.contributor.authorRafael D. L.; Monteiropt_BR
dc.contributor.authorJorge H. S. K.; Raimundopt_BR
dc.contributor.authorIvo M.pt_BR
dc.contributor.authorJr.; Mazalipt_BR
dc.contributor.authorItalo O.; Sigolipt_BR
dc.contributor.authorFernando A.pt_BR
unicamp.author.emailfsigoli@iqm.unicamp.brpt_BR
unicamp.authorSigoli, Fernando A.] Univ Estadual Campinas, Inst Chem, BR-13083970 Campinas, SP, Brazilpt_BR
unicamp.author.external[Gaspar, Rafael D. L.pt
unicamp.author.externalMonteiro, Jorge H. S. K.pt
unicamp.author.externalRaimundo, Ivo M., Jr.pt
unicamp.author.externalMazali, Italo O.pt
dc.subjectFullerene C-60-polystyrene Filmpt_BR
dc.subjectLaser Flash-photolysispt_BR
dc.subjectSensing Materialpt_BR
dc.subjectFluoropolymer Filmpt_BR
dc.subjectSensorspt_BR
dc.subjectFluorescencept_BR
dc.subjectPressurept_BR
dc.subjectLuminescencept_BR
dc.subjectMetalpt_BR
dc.subjectPolymerspt_BR
dc.description.abstractA new oxygen-sensitive optical probe based on the [Tb(3,5-dcba) 3]center dot 1/2H(2)O (3,5-dcba = 3,5-dichlorobenzoate) complex, which is chemically attached to a phosphine-oxide-functionalized polydimethylsiloxane is presented. The hybrid material shows green emission and transparency in the visible range. The optically sensitive probe is photostable under excitation at 350 nm and shows the highest oxygen sensitivity, I-0/I-100 equal to 8.9 at 1 atm, among probes based on homonuclear lanthanide compounds. Furthermore its reversibility is demonstrated after several cycles ranging from 100% N-2 to 100% O-2 with response time of 8.5 s (N-2 -> O-2) and recovery time of 49.5 s (O-2 -> N-2).en
dc.relation.ispartofCHEMPLUSCHEMpt_BR
dc.publisher.countryWEINHEIMpt_BR
dc.publisherWILEY-V C H VERLAG GMBHpt_BR
dc.date.issued2015-DECpt_BR
dc.identifier.citationPhotostable, Oxygen-sensitive Optical Probe Based On A Homonuclear Terbium(iii) Complex Covalently Bound To Functionalized Polydimethylsiloxane. Wiley-v C H Verlag Gmbh, v. 80, p. 1721-1724 DEC-2015.pt_BR
dc.language.isoenpt_BR
dc.description.volume80pt_BR
dc.description.issuenumber12pt_BR
dc.description.firstpage1721pt_BR
dc.description.lastpage1724pt_BR
dc.rightsfechadopt_BR
dc.sourceWOSpt_BR
dc.identifier.issn2192-6506pt_BR
dc.identifier.wosidWOS:000368592800004pt_BR
dc.identifier.doi10.1002/cplu.201500296pt_BR
dc.identifier.urlhttp://onlinelibrary.wiley.com/doi/10.1002/cplu.201500296/epdfpt_BR
dc.description.sponsorshipCoordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)pt_BR
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)pt_BR
dc.description.sponsorshipFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)pt_BR
dc.description.sponsorship1Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)pt_BR
dc.description.sponsorship1Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)pt_BR
dc.description.sponsorship1Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)pt_BR
dc.date.available2016-06-07T13:35:17Z-
dc.date.accessioned2016-06-07T13:35:17Z-
dc.description.provenanceMade available in DSpace on 2016-06-07T13:35:17Z (GMT). No. of bitstreams: 1 wos_000368592800004.pdf: 789079 bytes, checksum: f05b2e22027c6aa6d03c3f4ed97ba431 (MD5) Previous issue date: 2015en
dc.identifier.urihttp://repositorio.unicamp.br/jspui/handle/REPOSIP/244095-
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