Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/241658
Type: Artigo de periódico
Title: Low-temperature Oxidation Of Methane On Pd-sn/zro2 Catalysts
Author: Lovon-Quintana
Juan J.; Santos
Joao B. O.; Lovon
Adriana S. P.; La-Salvia
Nathalia; Valenca
Gustavo P.
Abstract: Pd/ZrO2, Pd-Sn/ZrO2 and Sn/ZrO2 were prepared by incipient wetness using Pd(NO3)(2)center dot XH2O and SnC4H4O6 center dot XH2O as precursors, dried and calcined in static air at 500 degrees C, 800 degrees C or 1100 degrees C. The influence of Sn species in the oxygen storage capacity of the catalysts, distribution of Pd particle sizes and CH4 oxidation reaction were investigated. Pd particle size was larger on Sn-containing catalysts and showed lower mobility than those in the absence of Sn. Sn oxide species act as an oxygen reservoir that are easily transferred to Pd surfaces promoting the oxidation reaction of methane. For Pd-Sn-containing solids calcined at 1100 degrees C, the contribution of Sn in the CH4 oxidation reaction is negligible. (C) 2015 Published by Elsevier B.V.
Subject: Supported Palladium Catalysts
Noble-metal Catalysts
Surface-areas
Tin Oxide
Combustion
Hydrogen
Alumina
Oxygen
Pd
Chemisorption
Country: AMSTERDAM
Editor: ELSEVIER SCIENCE BV
Rights: embargo
Identifier DOI: 10.1016/j.molcata.2015.08.001
Address: http://www.sciencedirect.com/science/article/pii/S1381116915300480
Date Issue: 2016
Appears in Collections:Unicamp - Artigos e Outros Documentos

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