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Type: Artigo de periódico
Title: The determination of the stoichiometry of the mixed complex of vanadium with hydrogen peroxide and with 4-(2-Pyridilazo) Resorcinol
Author: He, Xiwen
Tubino, Matthieu
Rossi, Adriana Vitorino
Abstract: The present study reports details of the stoichiometric characterization of the mixed complex system, V(H2O2)PAR, formed when vanadium adequately reacts with hydrogen peroxide and with 4-(2-Pyridilazo)Resorcinol. Also the presence of polynuclear species was investigated in order to elucidate about unambiguous assignment of the molar absorptivity, stability constant and composition of the complex. Two mathematical treatments methods of the experimental results were employed. From the results it can be concluded that this system corresponds to a mononuclear complex with 1:1:1 stoichiometry.
Subject: vanadium
complex stoichiometry
Editor: Sociedade Brasileira de Química
Rights: aberto
Identifier DOI: 10.1590/S0100-40422000000300007
Date Issue: 1-Jun-2000
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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