Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/23422
Type: Artigo de periódico
Title: Termoquímica na Unicamp: depoimento sobre uma jornada de 25 anos
Title Alternative: Thermochemistry at Unicamp: testimony of a 25 year journey
Author: Chagas, Aécio Pereira
Airoldi, Claudio
Abstract: This article describes the progress of a group of investigation on thermochemistry, which started in 1972. A homemade calorimeter was employed to provide quantitative support to the information on interative effect between lanthanide cations and halides or pseudohalides, in non-aqueous solvents, previously derived from conductometric titrations. However, the features of this instrument were not able to detect the thermal effects. Therefore, the great input to the group came from the acquisition of an LKB commercial apparatus, by the University in 1975. Considering the historical development of the coordination chemistry in Brazil, which was previously dedicated to strutural features of adducts, without focusing the energetic envolved in any coordinationcompound. Since starting the thermochemistry study, numerous masters and doctoral thesis covering more than a hundred adducts and a reasonable number of chelates, were presented systematizing data in order to understand the behavior of this kind of coordination compounds (C. Airoldi and A. P. Chagas, Coord. Chem. Rev. 1992, 119, 29). This knowledge enabled an extension of the study to include some heterogeneous systems formed by natural or synthetic materials like immobilized silica gel, lamellar phosphate, phosphonate or sulphate compounds, clays, polysaccharides, chrysotile, soils, etc. Many students are now engaged as staff members in Universities, Research Instituitions or other private institutions, developing many activities. Due to a multiplying effect on the formation of researchers, the group is now reaching the fourth generation.
Subject: history of chemistry in Brazil
thermochemistry
adducts
Editor: Sociedade Brasileira de Química
Rights: aberto
Identifier DOI: 10.1590/S0100-40421999000300024
Address: http://dx.doi.org/10.1590/S0100-40421999000300024
http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40421999000300024
Date Issue: 1-Jun-1999
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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