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Type: Artigo de periódico
Title: Dba-free" Palladium Intermediates Of The Heck-matsuda Reaction."
Author: Machado, Angelo H L
Milagre, Humberto M S
Eberlin, Livia S
Sabino, Adão A
Correia, Carlos Roque D
Eberlin, Marcos N
Abstract: The dba-free Heck-Matsuda reaction was investigated via direct ESI-MS(/MS) monitoring. Palladium species involved in the reduction of Pd(II) during a Wacker type reaction and several dba-free arylpalladium transient complexes were detected and characterized. Based on these findings, a more comprehensible catalytic cycle for this pivotal reaction is suggested.
Subject: Molecular Structure
Organometallic Compounds
Spectrometry, Mass, Electrospray Ionization
Tandem Mass Spectrometry
Citation: Organic & Biomolecular Chemistry. v. 11, n. 20, p. 3277-81, 2013-May.
Rights: aberto
Identifier DOI: 10.1039/c3ob40142a
Date Issue: 2013
Appears in Collections:Unicamp - Artigos e Outros Documentos

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