Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/200537
Type: Artigo de periódico
Title: Dba-free" Palladium Intermediates Of The Heck-matsuda Reaction."
Author: Machado, Angelo H L
Milagre, Humberto M S
Eberlin, Livia S
Sabino, Adão A
Correia, Carlos Roque D
Eberlin, Marcos N
Abstract: The dba-free Heck-Matsuda reaction was investigated via direct ESI-MS(/MS) monitoring. Palladium species involved in the reduction of Pd(II) during a Wacker type reaction and several dba-free arylpalladium transient complexes were detected and characterized. Based on these findings, a more comprehensible catalytic cycle for this pivotal reaction is suggested.
Subject: Molecular Structure
Organometallic Compounds
Palladium
Spectrometry, Mass, Electrospray Ionization
Tandem Mass Spectrometry
Rights: aberto
Identifier DOI: 10.1039/c3ob40142a
Address: http://www.ncbi.nlm.nih.gov/pubmed/23511838
Date Issue: 2013
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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