Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/200535
Type: Artigo de periódico
Title: More On Polypseudorotaxanes Formed Between Poly(ethylene Glycol) And α-cyclodextrin.
Author: Sabadini, Edvaldo
Egídio, Fernanda do Carmo
Cosgrove, Terence
Abstract: A new interpretation for the mechanism associated with the spontaneous threading of α-CD, onto a PEG chain followed by the supramolecular hydrogel formation, is described. Beyond a specific stoichiometry, the complexation of α-CD and PEG results in the formation of a two-phase system. Besides the phase separation, for PEG with a molecular weight higher than 6000 Da, part of the polymer chains are unthreaded by the α-CD, leading to the formation of a supramolecular hydrogel. The kinetics for the complexation and the determination of the yield for equilibrated systems consisting of PEG (linear and star) are used to investigate the number of α-CD threaded before and after the phase separation. The results are compared with the prediction obtained from the application of the Poisson distribution and reveal the ratio between α-CD and PEG in each step of the process. Additionally, the kinetics for the hydrogel formation and its inner structure are investigated by using the proton NMR spin-spin relaxation of water.
Subject: Polyethylene Glycols
Rotaxanes
Alpha-cyclodextrins
Rights: fechado
Identifier DOI: 10.1021/la304910v
Address: http://www.ncbi.nlm.nih.gov/pubmed/23510502
Date Issue: 2013
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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