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Type: Artigo de periódico
Title: Quantitative Analysis By Comprehensive Two-dimensional Gas Chromatography Using Interval Multi-way Partial Least Squares Calibration.
Author: de Godoy, Luiz Antonio Fonseca
Pedroso, Marcio Pozzobon
Hantao, Leandro Wang
Poppi, Ronei Jesus
Augusto, Fabio
Abstract: A new approach for target quantitative analysis for comprehensive two-dimensional gas chromatography (GC × GC), interval Multi-way Partial Least Square (iNPLS) is presented and evaluated in this paper. In iNPLS, the two-dimensional chromatogram is split in small sections; each of these pieces is treated as an independent new chromatogram. Separated conventional NPLS calibration models for the concentration of the target analyte are built for each of the pieces of the whole chromatogram, and the best model is selected for quantitative analysis. An algorithm for iNPLS running on MatLab platform was written, preliminarily evaluated with using solutions of model compounds with different chemical properties and subsequently applied to quantify some allergens in perfume samples. The results were found to be adequate, and good precision and accuracy was obtained even for poorly resolved peaks.
Subject: Algorithms
Chromatography, Gas
Feasibility Studies
Least-squares Analysis
Statistics As Topic
Citation: Talanta. v. 83, n. 4, p. 1302-7, 2011-Jan.
Rights: fechado
Identifier DOI: 10.1016/j.talanta.2010.08.015
Date Issue: 2011
Appears in Collections:Unicamp - Artigos e Outros Documentos

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