Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/198452
Type: Artigo de periódico
Title: Highly Regio- And Stereoselective Heck Reaction Of Allylic Esters With Arenediazonium Salts: Application To The Synthesis Of Kavalactones.
Author: Moro, Angélica Venturini
Cardoso, Flávio Sega Pereira
Correia, Carlos Roque Duarte
Abstract: A highly efficient palladium-catalyzed Heck reaction of allylic esters with arenediazonium salts is described. The reaction proceeds under mild conditions, with excellent to total regio- and stereochemical control and with retention of the traditional leaving group. Furthermore, the generality of the present methodology is illustrated by the short total synthesis of the natural kavalactones, yangonine, (+/-)-methysticin, and (+/-)-dihydromethysticin.
Citation: Organic Letters. v. 11, n. 16, p. 3642-5, 2009-Aug.
Rights: fechado
Identifier DOI: 10.1021/ol901416e
Address: http://www.ncbi.nlm.nih.gov/pubmed/19719201
Date Issue: 2009
Appears in Collections:Unicamp - Artigos e Outros Documentos

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