Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/198420
Type: Artigo de periódico
Title: Application Of Natural And Modified Hectorite Clays As Adsorbents To Removal Of Cr(vi) From Aqueous Solution--thermodynamic And Equilibrium Study.
Author: Guerra, Denis L
Viana, Rúbia R
Airoldi, Claudio
Abstract: A hectorite (H) clay sample has been modified with 2-mercaptobenzimidazole (MBI) using homogeneous and heterogeneous routes. Both modification methodologies resulted in similar products, named H(HOM) and H(HET), respectively. These materials were characterized by CO(2) gas adsorption, elemental analysis, nuclear magnetic nuclei of carbon-13 and silicon-29. The effect of two variables (contact time and metal concentration) has been studied using batch technique at room temperature and pH 2.0. After achieving the best conditions for Cr(VI) adsorption, isotherms of this adsorbate on using the chosen adsorbents were obtained, which were fitted to non-linear Sips isotherm model. The maximum number of moles adsorbed was determined to be 11.63, 12.85 and 14.01 mmol g(-1) for H, H(HOM) and H(HET), respectively, reflecting the maximum adsorption order of H(HET)>H(HOM)>H. The energetic effects (Delta(int)H degrees , Delta(int)G degrees and Delta(int)S degrees ) caused by chromium ion adsorption were determined through calorimetric titrations.
Subject: Adsorption
Aluminum Silicates
Benzimidazoles
Calorimetry
Chromium
Hydrogen-ion Concentration
Magnetic Resonance Spectroscopy
Models, Chemical
Models, Statistical
Silicates
Solutions
Thermodynamics
Water Pollutants, Chemical
Water Purification
Rights: fechado
Identifier DOI: 10.1016/j.jhazmat.2009.07.016
Address: http://www.ncbi.nlm.nih.gov/pubmed/19643537
Date Issue: 2009
Appears in Collections:Unicamp - Artigos e Outros Documentos

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