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dc.contributor.CRUESPUNIVERSIDADE DE ESTADUAL DE CAMPINASpt_BR
dc.typeArtigo de periódicopt_BR
dc.titleTotal Synthesis Of (+)-crocacin D.pt_BR
dc.contributor.authorDias, Luiz Cpt_BR
dc.contributor.authorde Oliveira, Luciana Gpt_BR
dc.contributor.authorVilcachagua, Janaína Dpt_BR
dc.contributor.authorNigsch, Florianpt_BR
unicamp.authorLuiz C Dias, Instituto de Química, Universidade Estadual de Campinas, UNICAMP, C. P. 6154 Campinas, SP, Brazil. ldias@iqm.unicamp.brpt_BR
unicamp.author.externalLuciana G de Oliveira,pt
unicamp.author.externalJanaína D Vilcachagua,pt
unicamp.author.externalFlorian Nigsch,pt
dc.subjectAlkenespt_BR
dc.subjectAmidespt_BR
dc.subjectMolecular Conformationpt_BR
dc.subjectStereoisomerismpt_BR
dc.description.abstract[structure: see text] The total synthesis of (+)-crocacin D is described. The convergent asymmetric synthesis relies on the use of a Stille cross-coupling between an (E)-vinyl stannane with an (E)-vinyl iodide to establish the (E,E)-dienamide moiety followed by a mild and efficient copper-catalyzed coupling between (+)-crocacin C and a (Z)-vinyl iodide to establish the challenging (Z)-enamide function.en
dc.relation.ispartofThe Journal Of Organic Chemistrypt_BR
dc.relation.ispartofabbreviationJ. Org. Chem.pt_BR
dc.date.issued2005-Marpt_BR
dc.identifier.citationThe Journal Of Organic Chemistry. v. 70, n. 6, p. 2225-34, 2005-Mar.pt_BR
dc.language.isoengpt_BR
dc.description.volume70pt_BR
dc.description.firstpage2225-34pt_BR
dc.rightsfechadopt_BR
dc.sourcePubMedpt_BR
dc.identifier.issn0022-3263pt_BR
dc.identifier.doi10.1021/jo047732kpt_BR
dc.identifier.urlhttp://www.ncbi.nlm.nih.gov/pubmed/15760209pt_BR
dc.date.available2015-11-27T13:02:51Z-
dc.date.accessioned2015-11-27T13:02:51Z-
dc.description.provenanceMade available in DSpace on 2015-11-27T13:02:51Z (GMT). No. of bitstreams: 1 pmed_15760209.pdf: 282155 bytes, checksum: a6ff439148adb39c5cf68f80f5fd8ee9 (MD5) Previous issue date: 2005en
dc.identifier.urihttp://repositorio.unicamp.br/jspui/handle/REPOSIP/196617-
dc.identifier.idPubmed15760209pt_BR
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