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Type: Artigo de periódico
Title: Total Synthesis Of (+)-crocacin D.
Author: Dias, Luiz C
de Oliveira, Luciana G
Vilcachagua, Janaína D
Nigsch, Florian
Abstract: [structure: see text] The total synthesis of (+)-crocacin D is described. The convergent asymmetric synthesis relies on the use of a Stille cross-coupling between an (E)-vinyl stannane with an (E)-vinyl iodide to establish the (E,E)-dienamide moiety followed by a mild and efficient copper-catalyzed coupling between (+)-crocacin C and a (Z)-vinyl iodide to establish the challenging (Z)-enamide function.
Subject: Alkenes
Molecular Conformation
Citation: The Journal Of Organic Chemistry. v. 70, n. 6, p. 2225-34, 2005-Mar.
Rights: fechado
Identifier DOI: 10.1021/jo047732k
Date Issue: 2005
Appears in Collections:Unicamp - Artigos e Outros Documentos

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