Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/194793
Type: Artigo de periódico
Title: Photoassisted Electrochemical Degradation Of Organic Pollutants On A Dsa Type Oxide Electrode: Process Test For A Phenol Synthetic Solution And Its Application For The E1 Bleach Kraft Mill Effluent.
Author: Pelegrini, R T
Freire, R S
Duran, N
Bertazzoli, R
Abstract: In this paper, the performance of a photoassisted electrolysis process, for the degradation of organic pollutants, is investigated. Results obtained in this work have shown that the thermally prepared anode of titanium, coated with 70TiO2/30RuO2, exhibits photoactivity and may be used for the treatment of effluents. A synthetic phenol aqueous solution and a real paper mill industry effluent were treated. Kinetic analysis showed a synergetic effect of electrolysis and photocatalysis and degradation rates are an order of magnitude greater than the sum of the results reached by using both processes individually. Using a 125 W mercury bulb and 20 mA cm-2, the phenol concentration decayed 85% in 90 min and 70% reduction of TOC was obtained. In the application of the treatment process for the degradation of the E1 bleach Kraft mill effluent, total phenols were practically eliminated in a short period of processing time, and color, usually resistant to biological treatment, was reduced to 10% from its initial value measured in terms of absorbance. Reductions of AOX, COD, and BOD by 25%, 30%, and 35%, respectively, were also observed.
Subject: Catalysis
Disinfectants
Electrodes
Electrolysis
Industry
Kinetics
Organic Chemicals
Paper
Phenol
Photochemistry
Titanium
Waste Disposal, Fluid
Water Pollutants, Chemical
Rights: fechado
Identifier DOI: 
Address: http://www.ncbi.nlm.nih.gov/pubmed/11452621
Date Issue: 2001
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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