Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/108889
Type: Artigo de periódico
Title: Surface And Structural Features Of Pt/ceo 2-la 2o 3-al 2o 3 Catalysts For Partial Oxidation And Steam Reforming Of Methane
Author: Mortola V.B.
Damyanova S.
Zanchet D.
Bueno J.M.C.
Abstract: Mixed xCeO 2-yLa 2O 3-Al 2O 3 oxides (where x+y=12wt%) were prepared by sol-gel method. It was shown that the mixed oxides are suitable carriers for supported Pt catalysts. The catalytic performances of the catalysts were evaluated in the reaction of stem methane reforming (SMR) and partial oxidation of methane (POM). The effect of the support kind on the surface and structural properties, as well as on the redox and catalytic behavior of the catalyst was studied. It was shown that the coexistence of the Pt 0/Pt δ+ and Ce 4+/Ce 3+ redox couples leads to the increase of the CH 4 conversion and carbon resistance over Pt catalysts. The CeO 2-containing catalysts showed the highest TOFCH4 values in SMR in spite of the low metal dispersion that is related to the high capacity of the surface to carbon cleaning caused by the highest oxygen mobility at metal-support interface. The strong initial deactivation of alumina-supported Pt catalyst in POM was related to Pt sintering. © 2011 Elsevier B.V.
Editor: 
Rights: fechado
Identifier DOI: 10.1016/j.apcatb.2011.07.012
Address: http://www.scopus.com/inward/record.url?eid=2-s2.0-80052283956&partnerID=40&md5=58e6761b015ac468b28c3de62dc11d0d
Date Issue: 2011
Appears in Collections:Unicamp - Artigos e Outros Documentos

Files in This Item:
File SizeFormat 
2-s2.0-80052283956.pdf2.22 MBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.