Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/107429
Type: Artigo de periódico
Title: Gaseous Sf3 +: An Efficient Electrophilic Monofluorinating Agent For Five-membered Heteroaromatic Compounds
Author: Gozzo F.C.
Ifa D.R.
Eberlin M.N.
Abstract: Reactions of gaseous SF3 + ions with furan, thiophene, pyrrole, and several of their alkyl derivatives were performed via MS2 experiments and found to occur readily both by electron abstraction and F+ transfer. Then, by performing MS3 experiments, the F+ transfer products - the protonated monofluorinated molecules - were mass-selected and deprotonated by a second reaction with a stronger base. F+ transfer from gaseous SF3 + followed by deprotonation promotes therefore C-H by C-F replacement in five-membered heteroaromatic compounds and the efficient gas-phase synthesis of their neutral monofluorinated derivatives.
Editor: 
Rights: fechado
Identifier DOI: 10.1021/jo9917442
Address: http://www.scopus.com/inward/record.url?eid=2-s2.0-0034733119&partnerID=40&md5=ed56cf3b5b331290767eda57421ce17e
Date Issue: 2000
Appears in Collections:Unicamp - Artigos e Outros Documentos

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