Please use this identifier to cite or link to this item:
Type: Artigo de periódico
Title: Non-occurrence Of A Zincke-like Process Upon Treatment Of 1-(2,4-dinitrophenyl)-3-methylimidazolium Chloride With A Chiral Primary Amine
Author: Pastre J.C.
Correia C.R.D.
Genisson Y.
Abstract: Huang's preparation of chiral imidazolium salts by means of a Zincke-like process was re-investigated. It was shown that treatment of 1-(2,4- dinitrophenyl)-3-methylimidazolium chloride with l-alaninol gives rise to complete decomposition of the starting salt via an SNAr reaction and that the material described by Huang was not the claimed chiral imidazolium salt, thus questioning the occurrence of the ionic liquids reported in the original work. © The Royal Society of Chemistry.
Rights: aberto
Identifier DOI: 10.1039/b804650f
Date Issue: 2008
Appears in Collections:Unicamp - Artigos e Outros Documentos

Files in This Item:
There are no files associated with this item.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.