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|Type:||Artigo de periódico|
|Title:||Non-occurrence Of A Zincke-like Process Upon Treatment Of 1-(2,4-dinitrophenyl)-3-methylimidazolium Chloride With A Chiral Primary Amine|
|Abstract:||Huang's preparation of chiral imidazolium salts by means of a Zincke-like process was re-investigated. It was shown that treatment of 1-(2,4- dinitrophenyl)-3-methylimidazolium chloride with l-alaninol gives rise to complete decomposition of the starting salt via an SNAr reaction and that the material described by Huang was not the claimed chiral imidazolium salt, thus questioning the occurrence of the ionic liquids reported in the original work. © The Royal Society of Chemistry.|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
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