Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/105107
Type: Artigo de periódico
Title: Regio- And Stereoselective Heck Arylations Of N-carbomethoxy-l-3- Dehydroproline Methyl Ester With Arenediazonium Salts. Total Synthesis Of Neuroexcitatory Aryl Kainoids
Author: Da Silva K.P.
Godoi M.N.
Correia C.R.D.
Abstract: The Heck arylation of N-carbomethoxy-L-3-dehydroproline methyl ester with arenediazonium tetrafluoroborates produced chiral 4-aryldehydroproline derivatives in moderate to good yields in a highly regio- and stereocontrolled fashion. A rationale for the unexpected high regioselectivity is provided using Deeth's model. Heck adduct 15 (G = o-CH3O) was converted into several aryl kainoids using concise and efficient routes. © 2007 American Chemical Society.
Editor: 
Rights: fechado
Identifier DOI: 10.1021/ol070980t
Address: http://www.scopus.com/inward/record.url?eid=2-s2.0-34547196841&partnerID=40&md5=4b3657fb2ddcf2d1ce2bda5b7c841e66
Date Issue: 2007
Appears in Collections:Unicamp - Artigos e Outros Documentos

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