Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/103190
Type: Artigo de periódico
Title: Enantioselective Catalytic Allylation And Crotylation Of Aldehydes [alilação E Crotilação Catalítica E Enantiosseletiva De Aldeídos]
Author: De Fatima A.
Robello L.G.
Pilli R.A.
Abstract: The field of chiral catalysis has experienced explosive growth over the last two decades. By now, many of the classical reactions in organic synthesis can be carried out efficiently in asymmetric manner. As one of the fundamental and powerful C-C bond-forming reactions, enantioselective catalytic allylation (ECA) and crotylation (ECC) of aldehydes has attracted considerable attention. In this article, we present an overview about the importance of chiral Lewis acids and bases in catalytic enantioselective addition of allyl- and crotyl metals to aldehydes and the application of this methodology in the total synthesis of natural and non-natural products.
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Rights: aberto
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Address: http://www.scopus.com/inward/record.url?eid=2-s2.0-33749562094&partnerID=40&md5=3825e8963332c425c1a322d2bd02f38d
Date Issue: 2006
Appears in Collections:Unicamp - Artigos e Outros Documentos

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