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Type: Artigo de evento
Title: Investigation On Kinetics Of Thermal Decomposition In Polysiloxane Networks Used As Precursors Of Silicon Oxycarbide Glasses
Author: Schiavon M.A.
Redondo S.U.A.
Pina S.R.O.
Yoshida I.V.P.
Abstract: In this study, polysiloxane networks prepared by hydrosilylation or hydrolysis/condensation reactions were considered to be potential precursors for Si-C-O systems. Different precursors had different pyrolytic properties, which was essentially due to their molecular architecture. The kinetics parameters, such as the activation energy, E (kJ/mol) involved in the polymer-to-ceramic conversion, were investigated by thermogravimetry using a multiple heating rate kinetic method. The relationships between the molecular architecture and the precursor composition were compared to that of a linear poly(dimethylsiloxane) precursor. Solid-state 29Si nuclear magnetic resonance, infrared spectroscopies, density measurements, and X-ray diffraction measurements were made on the final samples. These products were typically amorphous, with a molecular structure formed by a random distribution of different silicon sites and variable amounts of free carbon residue. © 2002 Elsevier Science B.V. All rights reserved.
Rights: fechado
Identifier DOI: 10.1016/S0022-3093(02)01009-8
Date Issue: 2002
Appears in Collections:Unicamp - Artigos e Outros Documentos

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