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Type: Artigo de periódico
Title: Synthesis Of Characterization Of Mapo-11 Molecular Sieves
Author: Fernandez R.
Giotto M.
Pastore H.
Cardoso D.
Abstract: In this work MAPO-11 molecular sieve was prepared with several degrees of magnesium substitution. The syntheses were carried by using phosphoric acid, pseudo-boehmite and magnesium acetate as sources of structural elements and diisopropylamine as the structure-directing agent. The samples were characterized by powder X-ray diffraction, thermogravimetry, infrared spectroscopy, solid-state nuclear magnetic resonance, scanning electron microscopy and elemental analysis. The X-ray diffractograms indicate that the AEL structure is obtained free of contaminating phases up to a magnesium molar ratio of 0.3 in the reaction mixture. Higher levels of magnesium cause the formation of other phases. Thermogravimetry, MAS nuclear magnetic resonance of 31P and infrared spectroscopy confirm the magnesium isomorphous substitution for aluminum up to this magnesium content in the reaction mixture. © 2002 Published by Elsevier Science Inc.
Rights: fechado
Identifier DOI: 10.1016/S1387-1811(02)00333-5
Date Issue: 2002
Appears in Collections:Unicamp - Artigos e Outros Documentos

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