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Type: Artigo de evento
Title: Micro- And Nanocomposites Of Keggin Heteropolymetalates In Cellulose Esters
Author: De Oliveira F.C.
Schneider J.
Siervo A.
Landers R.
Plepis A.M.G.
Pireaux J.-J.
Rodrigues-Filho U.P.
Abstract: Composites of Keggin heteropolymetalates have been prepared and characterized by SEM, XPS, 31P-magic angle spinning/nuclear magnetic resonance and differential scanning calorimetry. The phosphotungstic acid and phosphomolybdic acid form nanocomposites where the oxocluster structure is preserved and is highly dispersed over the material, probably inserted between the polymeric chains. Phosphovanadotungstic clusters suffer partial decomposition during composite formation, resulting in a biphasic microcomposite. The decomposition product, phosphotungstic acid presents surface segregation as shown by comparison of XPS and nuclear magnetic resonance results.
Rights: fechado
Identifier DOI: 10.1002/sia.1364
Date Issue: 2002
Appears in Collections:Unicamp - Artigos e Outros Documentos

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